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Q.

Autoprotolysis constant of a weak acid HA is 4x 10-8. Hence, [A-] is

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a

2×104M

b

0.25×106M

c

16×1016M

d

4×108M

answer is A.

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Detailed Solution

In autoprotolysis, a proton is transferred between two identical molecules:

HA+HAH2A+A H2A=A K=H2AA=4×108 H2A2=A2=4×108 A=2×104M

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