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Q.

B2H6 + NaH  ? 

The correct statement(s) is / are

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a

Symmetrical cleavage takes place

b

NaBH4 is produced

c

H2 is produced

d

Both 1 and 2

answer is D.

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Detailed Solution

The reaction of diborane (B2H6) with NaH is NaBH4(sodium borohydride). 

B2H6 + 2NaH  2NaBH4  

Diborane can be cleaved either symmetrically or unsymmetrically. Symmetrical cleavage of diborane results in the formation of a covalent compound whereas unsymmetrical cleavage of diborane forms an ionic compound. Sodium borohydride is a covalent compound, hence there is a symmetrical cleavage of diborane when it reacts with NaH.

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