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Q.

BaCO3(s)+AcOHNa2C2O4 solution Δ?

Comment on the product of this reaction:

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a

BaCO3 remains unaffected.

b

BaC2O4 will be precipitated as white precipitate 

c

Ba(OAc)2 will be precipitated as white precipitate 

d

Clear solution

answer is D.

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Detailed Solution

Ba2++C2O42BaC2O4(white ppt.)

                 (Soluble in AcOH and H2C2O4 ) 

Note : CaC2O4is insoluble in  dil. AcOH,H2C2O4  and NH42C2O4 solution, but soluble in  dil. HCl and  dil. HNO3

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