Q.

Balancing the following equation
Cr(OH)3+IO3OHI+CrO42
(or)
Balance the above equation basic medium.

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Detailed Solution

Equation
Question Image
Oxidation half reaction Cr(OH)3CrO42
1) Balance the atoms other than H and O
Cr(OH)3CrO42
2) Balance of oxygen atoms
Cr(OH)3+H2OCrO42
3) Balance of Hydrogen atoms
Cr(OH)3+H2O+5OHCrO42+5H2O
4) Balance of charges
Cr(OH)3+5OH+H2OCrO42+5H2O+3e(1)
Reduction half reaction  IO3I
1) Balance the atoms other than H and O
IO3I
2) Balance of oxygen atoms
IO3I+3H2O
3) Balance of Hydrogen atoms
IO3+6H2OI+3H2O+6OH
4) Balance of charges
IO3+6H2O+6eI+6OH+3H2O(2)
(1×2)
2Cr(OH)3+10OH+2H2O2CrO42+10H2O+6e.....(3)
IO3+6H2O+6eI+6OH+3H2O.....(4)
eq(3) + eq(4)
2Cr(OH)3+IO3+8H2+4OH2CrO42+I+13H2O
Simplify the above equation
2Cr(OH)3+IO3+4OH2CrO42+I+5H2O

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