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Q.

Balmer gives an equation for wavelength of visible radiation of H-spectrum as  λ=kn2n24. The value of k in terms of Rydberg’s constant R is 

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a

4R

b

R

c

R/4

d

4/R

answer is D.

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Detailed Solution

1λ  =  RZ21n12  1n22.  For  Hatom  Z=1.

For visible radiation, n1=2

    1λ  =  R12 2  1n 2  λ=4n2Rn24=k  n2n24    k=4R.

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