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Q.

Barium ions, CNand Co2+form a water soluble ionic complex with Ba2+as free cation. For a 0.01M solution of this complex osmotic pressure is observed to be equal to 0.984 atm and degree of dissociation is found to be 75%. Then find the coordination number of Co(II) in this complex. T=300KR=0.082   L  atm  mol1K1

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answer is 5.

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Detailed Solution

π=i CRT0.984=i×0.01×0.082×300 0.984=i×0.01×0.082×300i=0.9840.246=4α=i1n10.75=41n1n=5
So complex contains 5 ions per molecule.
Complex can be Ba3Co(CN)52
 

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Barium ions, CN−and Co2+form a water soluble ionic complex with Ba2+as free cation. For a 0.01M solution of this complex osmotic pressure is observed to be equal to 0.984 atm and degree of dissociation is found to be 75%. Then find the coordination number of Co(II) in this complex. T=300KR=0.082   L  atm  mol−1K−1