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Q.

Based on the value of B.E. Given, 

fH0 of N2H4(g) is: Given BE of : N-N is 159 kJ mol-1; H-H is 436 kJ mol-1; N=N is 941 kJ mol-1; N-H is 398 kJ mol-1

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a

711 kJ mol-1

b

62 kJ mol-1

c

-98kJ mol-1

d

-711 kJ mol-1

answer is B.

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Detailed Solution

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H( bond breaking )=ΔH(N)+2ΔH(HH)=941+2(436)=1813

ΔH( bond formation )=[ΔH(NN)+4ΔH(NH)]=[159+4(398)]=1751

ΔH=ΔH( bond formation )+ΔH( bond breaking )=1751+1813=62kJ/mol

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