Q.

BCl3  is a planar molecule whereas NCl3 is pyramidal because

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a

B-Cl bond is more polar than N-Cl bond

b

BCl3  has no lone pair but NCl3  has a lone pair of electrons on central atom

c

Nitrogen atom is smaller than boron atom

d

N-Cl bond is more covalent than B – Cl bond

answer is B.

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BCl3  is a planar molecule whereas NCl3 is pyramidal because