Q.

BCl3 does not exist as dimer but BH3 exist as dimer because

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a

Cl is more electropossitive than H

b

There is    back bonding in BCl3 but BH3 does not contain such multiple bonding

c

Large chlorine atoms do not fit between small sized boron atoms whereas small hydrogen atoms get fitted between boron atoms

d

None of these

answer is B.

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Detailed Solution

BCl3 does not exist as dimer but BH3 exist as dimer because There is    back bonding in BCl3 but BH3 does not contain such multiple bonding.

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BCl3 does not exist as dimer but BH3 exist as dimer because