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Q.

BeC2O4 and BaC2O4  are heated separately with Bunsen burner. The solid residue obtained are respectively:

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a

BeO and BaO

b

BeO and  BaCO3

c

BeCO3 and  BaCO3

d

BeCO3 and BaO3

answer is B.

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Detailed Solution

The compound beryllium oxalate trihydrate decomposes on heat treatment to beryllium oxide.

There was some indication of intermediate compounds existing in the decomposition of the BeO.

By decomposing the beryllium oxalates at various temperatures, the surface area of the solid residue increases with a loss of crystal morphology.

The following reaction is obtained when BeC2O4 and  BaC2O4 are heated, 

BeC2O4ΔBeO+COBaC2O4ΔBaCO3+CO

Hence BeO and BaCO3 obtained as the result when  BeC2O4 and BaC2O4 are heated separately.

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