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Q.

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Behave as acid are well as reducing agent. Then which of the following are the correct statements regarding 

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a

When behaves as reducing agent, then its equivalent weights are equal to half of its molecular weight respectively

b

1000 mL of 1M solution is neutralized by 1000 mL of 1M  Ca(OH)2

c

1000 mL of 1M solution is neutralized by 200 mL 2M of  KMnO4 in acidic medium

d

1000 mL of 1N solution of each is neutralized by 1000 mL 1N  Ca(OH)2

answer is A, B, D.

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Detailed Solution

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When behave as reducing agent (COOH)22CO2

 n-factor = 2, eq wt. = M/2

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n-factor = 2, eq wt. = M/2

for neutralization meq of one reactant = meq of other reactant can be neutralized 

1000×2=1000×2

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