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Q.

Benzene and naphthalene form an ideal solution at room temperature. For this process, the true statement (s) is (are)
(i) $Δ G$ is positive
(ii) $Δ S$ _systemis positive
(iii) $Δ S$ _surroundings=0
(iv) $Δ H$ = 0

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a

(ii) and (iv) only

b

(i) and (iii) only

c

(ii), (iii) and (iv) only

d

all of these

answer is C.

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Detailed Solution

For an ideal solution,

(i) $Δ G < 0$ : for mixing

(ii) $Δ S$ _system>0: because disorder increases

(iii) $Δ S$ _SURR =0: no heat is exchanged in case of ideal solution

(iv) $Δ H_{m i x} = 0$

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Benzene and naphthalene form an ideal solution at room temperature. For this process, the true statement (s) is (are)(i) ΔG is positive (ii) ΔS system is positive(iii) ΔS surroundings=0 (iv) ΔH= 0