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Q.

Benzene Conc.HNO3,<60°CConc.H2SO4AdarkCI2, FeCI3B.Incorrect statement is

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a

A is less reactive than benzene towards electrophilic substitution

b

B is p-chloronitrobenzene

c

Electrophile in the formation of ‘A’ is nitronium ion

d

A → B is electrophilic substitution

answer is A.

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Detailed Solution

  • Benzene reacts with concentrated nitric acid at 323-333K in the presence of concentrated sulphuric acid to form nitrobenzene.
  • Nitro benzene reacts chlorine in presence of FeCl3 to give m- chloro nitro benzene. 
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