Benzene →Conc.HNO3,<60°CConc.H2SO4A→darkCI2, FeCI3B.Incorrect statement is

Benzene reacts with concentrated nitric acid at 323-333K in the presence of concentrated sulphuric acid to form nitrobenzene.Nitro benzene reacts chlorine in presence of FeCl3 to give m- chloro nitro benzene.

Benzene →Conc.HNO3,<60°CConc.H2SO4A→darkCI2, FeCI3B.Incorrect statement is

Benzene reacts with concentrated nitric acid at 323-333K in the presence of concentrated sulphuric acid to form nitrobenzene.Nitro benzene reacts chlorine in presence of FeCl3 to give m- chloro nitro benzene.

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$Benzene \to_{Conc . {HNO}_{3}, < 60 ° C}^{Conc . H_{2} {SO}_{4}} A \to_{dark}^{{CI}_{2}, {FeCI}_{3}} B .$ Incorrect statement is

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A is less reactive than benzene towards electrophilic substitution

B is p-chloronitrobenzene

Electrophile in the formation of ‘A’ is nitronium ion

A → B is electrophilic substitution

answer is A.

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Detailed Solution

Benzene reacts with concentrated nitric acid at 323-333K in the presence of concentrated sulphuric acid to form nitrobenzene.
Nitro benzene reacts chlorine in presence of FeCl₃to give m- chloro nitro benzene.

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