Q.

Benzene on nitration gives nitrobenzene in presence of HNO3 and H2SO4 mixture, where:

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a

HNO3 acts as an acid and  H2SO4 acts as a base

b

HNO3 acts as a base and H2SO4 acts as an acid

c

Both H2SO4 and HNO3 act as an acids

d

Both H2SO4 and HNO3 act as a bases

answer is C.

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Detailed Solution

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Due to the larger acid dissociation constant (Ka) sulphuric acid acts as an acid and HNO3 acts as a base. 

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Benzene on nitration gives nitrobenzene in presence of HNO3 and H2SO4 mixture, where: