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Q.

Benzyl alcohol and sodium benzoate is obtained by the action of sodium hydroxide on benzaldehyde. This reaction is known as

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a

Sandmeyers reaction

b

Perkin's reaction

c

Cannizzaro's reaction

d

Claisen condensation

answer is B.

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Detailed Solution

Benzaldehyde on treatment with 50% aqueous or ethanolic alkali solution undergoes Cannizzaro's reaction like HCHO (no α-hydrogen atom), i.e., one molecule is oxidized and one is reduced with the formation of benzoic acid and benzyl alcohol respectively.

2C6H5CHO NaOH C6H5CH2OH+C6H5COONa

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