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Q.

Benzyl alcohol is obtained from benzaldehyde by 

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a

Fitting reaction 

b

Wurt's reaction

c

Kolbe’s reaction 

d

Cannizzaro reaction 

answer is B.

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Detailed Solution

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Benzaldehyde is treated with strong base like NaOH (Disproportionation reaction) 

This is called Cannizzaro’s reaction. In this reaction benzoyl chloride and sodium benzoate is produced which on hydrolysis gives 

C6H5CHO+NaOHC6H5CH2OH+C6H5COONa

Benzaldehyde Benzoyl alcohol Sodium Benzoate.

Therefore, the correct answer is option (B) Cannizzaro’s reaction.

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