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Q.

Berry pseudorotation is not observed in :

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a

${PF}_{4} Cl$

b

$(C H_{3}))_{3} F_{2}$

c

$\begin{array}{l} C {H_{3} PPF}_{4} \end{array}$

d

${PF}_{5}$

answer is C.

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Detailed Solution

In $(C H_{3})_{3} P F_{2}$ (Trimethylindium pyrimidine), when B.P.R. occurs, $C H_{3}$ will occupy axial position, which is not possible.
Hence correct option is c.

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Berry pseudorotation is not observed in :