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Q.

Bleaching powder and bleach solution are produced on a large scale and used in several household products. The effectiveness of bleach solution is often measured by iodometry.

25 mL of household bleach solution was mixed with 30 mL of 0.50 M KI and 10 mL of 4 N acetic acid. In the titration of the liberated iodine, 48 mL of0.25 N Na2S2O3was used to reach the end point. The molarity of the household bleach solution is:

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a

0.024 M

b

0.48 M

c

0.96 M

d

0.24 M

answer is C.

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Detailed Solution

Milli equivalent of KI used=48×0.25=12

CaOCl2+2AcOHCa(OAc)2+H2O+Cl2

Cl2+2KI2KCl+I2

I2+2Na2S2O3Na2S4O6+2NaI

mmol of Cl2=mmol of CaOCl2=122=25×M

Thus, option C is correct.

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