Banner 0
Banner 1
Banner 2
Banner 3
Banner 4
Banner 5
Banner 6
Banner 7
Banner 8
Banner 9

Q.

Bond angle is 1110 in

see full answer

Your Exam Success, Personally Taken Care Of

1:1 expert mentors customize learning to your strength and weaknesses – so you score higher in school , IIT JEE and NEET entrance exams.
An Intiative by Sri Chaitanya

a

ClO2-

b

ClO3-

c

ClO-

d

ClO4-

answer is A.

(Unlock A.I Detailed Solution for FREE)

Best Courses for You

JEE

JEE

NEET

NEET

Foundation JEE

Foundation JEE

Foundation NEET

Foundation NEET

CBSE

CBSE

Detailed Solution

All oxo acids of Chlorine are monobasic….contain one O-H group/molecule ;

All the pi bonds in these acids or their oxanions are - bonds ;

In all oxo acids of Chlorine the hybridization of Chlorine atom is sp3 ;

Cl-O bond  order….ClO- 1<ClO2-1.5 <ClO2- 1.66<ClO4-1.75 ;

No resonance in Hypochlorite ion, two resonance structures in Chlorite ion, three resonance structures in Chlorate ion, four resonance structures in Perchlorate ion ;

Cl-O bond length….ClO->ClO2->ClO3->ClO4- ;

Bond angle….ClO--no bond angle …. diatomic speciesClO3-- 1070 (3 bp+ 1 lp )ClO4-- 109.50(4 bp); In ClO2- - 1110( 2 bp + 2 lp ).bp-bp repulsions dominate lp-lp repulsions ;

Acidic strength, oxidizing power, bleaching power…..HClO>HClO2>HClO3>HClO3 ;

Basic strength…….ClO->ClO2->ClO3->ClO4- ;

ClO- does not exhibit resonance ; ClO4- cannot undergo disproportionation…'Cl' is in its highest O.S ;

Stability….HClO<HClO2<HClO3<HClO4;

Note : While counting the sigma bonds in these acids never forget to count a sigma bond between O-H bond ; 

Question Image

Number of bond pairs around central atom = 3
Number of bond pairs around central atom according to VSPER theory =2
Number of lone pairs around central atom = 2
Orientation of electron pairs around central atom = Tetrahedral(sp3)
Shape of ClO2-= Angular
Cl–O bond order = 3/2 = 1.5
It has two resonance structures.

Watch 3-min video & get full concept clarity
score_test_img

courses

No courses found

Ready to Test Your Skills?

Check your Performance Today with our Free Mock Test used by Toppers!

Take Free Test

Get Expert Academic Guidance – Connect with a Counselor Today!

best study material, now at your finger tips!

  • promsvg

    live classes

  • promsvg

    progress tracking

  • promsvg

    24x7 mentored guidance

  • promsvg

    study plan analysis

download the app

gplay
mentor

Download the App

gplay
whats app icon
personalised 1:1 online tutoring