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Q.

Bond dissociation enthalpy (BDE) is the change in enthalpy, when one mole of identical covalent bonds broken to form free radicals in gas phase. In case of polyatomic molecules, bond dissociation enthalpy is different for different bonds within the same molecule. Bond dissociation energy is affected by s orbital character involved in bonding atoms. Use the following data.

Cl2(g) 2Cl(g)ΔH0=242kJ/mol
CH4(g)C(g)+4H(g)ΔH0=1665kJ/mol
H2(g)2H(g)ΔH0=435kJ/mol
Cl3CH(g)Cl3C(g)+H(g)ΔH0=347kJ/mol
HCl(g)H(g)+Cl(g)ΔH0=431kJ/mol
Cl3CCl(g)Cl3C(g)+Cl(g)ΔH0=431kJ/mol

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