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Q.

Bond length order is

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a

$- C_{|}^{|} - C_{|}^{|} - > C = C < > - C \equiv C -$

b

$- C \equiv C - > > C = C < > - C_{|}^{|} - - C_{|}^{|} -$

c

$C_{|}^{|} - C_{|}^{|} - < > C = C < > - C \equiv C -$

d

$- C_{|}^{|} - C_{|}^{|} - > > C = C < = - C \equiv C -$

answer is A.

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Detailed Solution

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The carbon–carbon (C–C) bond length in single bond is 154 pm or we can say 1.54 A⁰ ,C=C bond length is 134 pm. But in benzene all C-C bond lengths are equal to 139 pm due to resonance. The carbon-carbon triple bond or multiple bond in acetylene is the shortest (120 pm) and the strongest. The carbon - carbon bond length in graphite is 142 pm or 1.42 A⁰.

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