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Q.

Boron does not form B3+ ions whereas Al forms Al3+ ions. This is because

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a

The sum of IE1 + IE2 + IE3 of B is much higher than that of Al

b

The size of B atom is larger than that of Al

c

Both 1 and 2

d

The sum of IE1 + IE2 + IE3 of Al is much higher than that of B

answer is B.

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Detailed Solution

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  • Due to small size of boron, the sum of its first three ionization enthalpies is very high. 
  • This prevents it to form +3 ions and forces it to form only covalent compounds. 
  • But as we move from B to Al, the sum of the first three ionization enthalpies of Al considerably decreases and is therefore able to form Al3+ ions.
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