Q.

Both 'Li' and 'Mg' display several similar properties due to the diagonal relationship however they are   incorrect in with respect to 

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a

Bort form nitrides

b

Nitrates of both gives NO2 and O2 on heating

c

 Both form form soluble bicarbonates

d

Both  form basic carbonates

answer is A.

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Detailed Solution

1. Magnesium forms basic carbonates (MgCO3​.Mg(OH)2​.xH2​O) while lithium forms normal carbonates, it does not form basic carbonates. 

5Mg+2+6CO23+7H2O4MgCO3Mg(OH)25H2O+2HCO3

While Li can form only carbonate (Li2CO3)  not basic carbonate

2.Both Li and Mg combine directly with N2​ to give nitrides Li3​N2​ and Mg3​N2​

3.Bicarbonates of Li and Mg are more soluble in water than carbonates whereas carbonates of alkali metals are more soluble.

4.Hydroxides and nitrates of both Li and Mg decompose on heating to give oxide.

LiNO3​Li2​O+NO2​+O2

Mg(NO3​)2​ ​MgO+NO2​+O2

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