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Q.

Both NF3  and  NCl3  are covalent but they differ in the extent of hydrolysis because

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a

Electronegativity of fluorine is greater than chlorine

b

NF3  is more stable than NCl3  and hydrolysis product of NF3 , HOF do not exist

c

Dipolemoment of NF3  is greater than that of  NCl3 

d

Chlorine can expand its octet by using d-orbitals

answer is D.

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Detailed Solution

In NF3 both N and F atoms do not contain d orbitals but in  NCl3,  chlorine atom contain vacant 3d orbitals with which water molecules can interact.

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Both NF3  and  NCl3  are covalent but they differ in the extent of hydrolysis because