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Q.

Both Co3+and Pt4+ have a co-ordination number of six, which of the following pair of complexes will show approximately the same electrical conductance for their 0.001M aqueous solution?

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a

CoCl36NH3 and PtCl43NH3

b

CoCl36NH3 and PtCl45NH3

c

CoCl33NH3 and PtCl45NH3

d

CoCl34NH3 and PtCl44NH3

answer is C.

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Detailed Solution

Both CoCl3.6NH3 and PtCl4.5NH3 will have the same electrical conductance for their 0.001 M aqueous solutions because they produce the same amount of ions upon dissociation.

CoCl3.NH3[Co(NH3)6](3+)+3Cl-

PtCl4.5NH3[Pt(NH3)5Cl(3+)+3Cl-

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