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Q.

Bromo ethane is heated with metallic sodium in dry ether to form ‘X’. Total number of isomers obtained when ‘X’ is subjected to mono bromination is

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a

2

b

1

c

3

d

4

answer is C.

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Detailed Solution

This is Wurtz reaction,the product is n-butane;

n-butane on mono bromination gives,

${CH}_{3} - {CH}_{2} - {CH}_{2} - {CH}_{2} - Br; {CH}_{3} - \overset{*}{C} H (Br) - {CH}_{2} - {CH}_{3} (d and l); Total isomers = 3$

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Bromo ethane is heated with metallic sodium in dry ether to form ‘X’. Total number of isomers obtained when ‘X’ is subjected to mono bromination is