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Q.

Brown ppt. (A} lf II group sulphide dissolves inHNO3, gives (B) which gives white ppt. ( C) with

NH4OH. (C) on reaction with HCl gives solution (D) which gives white turbidity on addition of water. What is (D}?

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a

Bi(OH)3

b

BiCl3

c

BiOCl

d

BiNO33

answer is A.

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Detailed Solution

Bi2S3(A)⟶HNO3BiNO33(B)⟶NH4OHBi(OH)3(White ppt)↓ Bi(OH)3→HClBiCl3(D)←H2OBiOCl(White turbidity)

 

                                                            

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