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Q.

Buff colored cyanide compound (A) reacts with excess of KCN in presence of an oxidizing agent gives (B). Which d orbitals is/ are participating in hybridization of complex (B)?

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a

dyz

b

dzx

c

dxy

d

dz2

answer is D.

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Detailed Solution

Co2++2CNCo(CN)2(buff colored ppt.)excess CN-                             Co(CN)64O2Co(CN)63d3sp3

d orbitals participating in hybridization of complex is dz2.

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