Q.

By using which of the following whether a given ligand is strong field or weak field can be determined.

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a

By the preparation of an octahedral Cr2+  complex

b

By the preparation of an octahedral  Cr3+ complex

c

By using visible spectra of either  Cr2+ or Ni2+  complexes 

d

By the preparation of an octahedral Ni2+  complex

answer is A, D.

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Detailed Solution

Octahedral Cr2+ complexes should be used. High spin or weak field  Cr2+ complexes have 4 unpaired electrons but low spin (strong field)  Cr2+ complexes have 2 unpaired electrons. Octahedral  Ni2+ complexes cannot be used to distinguish weak – from stron – field ligands by examining magnetic properties. By using the visible spectra of the complexes, the strength of ligand can be decided depending on splitting energy.

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