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Q.

C2H5BrAgCNAH3O+HCOOH+BCHCl3/KOHAreductionC (on reduction)

A,B,C respectively in the above sequence are

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a

Ethane amine, methane nitrile and diethylamine

b

Carbyl amino ethane, ethanamine and secondary amine

c

Ethyl isocyanide, ethyl amine and methyl isocyanate

d

Carbylaminoethane, ethanamine, and ethyl methyl amine

answer is D.

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Detailed Solution

A is carbyl aminoethane, B is ethanamine, and C is ethyl methyl amine.

 Ethyl bromide in reaction with silver cyanide gives carbyl amino ethane, which upon further acidic hydrolysis gives HCOOH and ethanamine. Ethanamine in addition to KOH and chloroform gives carbyl amino ethane which on further reduction gives ethyl methyl amine.

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