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Q.

C2H5Cl  AgNO2 X (major);
C2H5Cl  KCN Y (major);
Number of dative bonds in X and Y are respectively

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a

0,1

b

1,1

c

1,0

d

0,0

answer is D.

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Detailed Solution

Chemistry Problem: Number of Dative Bonds in X and Y

First Reaction: C2H5Cl + AgNO2 → X (major)

  • AgNO2 provides the NO2 ion which is ambident (can bond through N or O).
  • With AgNO2, the alkyl group attaches usually through oxygen, yielding ethyl nitrite (C2H5ONO).
  • Structure of X: Ethyl nitrite (C2H5ONO).
  • In ethyl nitrite, a dative bond exists between oxygen and nitrogen in the ONO group.
  • Number of dative bonds in X: 1

Second Reaction: C2H5Cl + KCN → Y (major)

  • KCN provides CN ion, which nucleophilically attacks via carbon.
  • The product is ethyl cyanide (C2H5CN).
  • There are only normal covalent bonds between C, H, and N atoms, no dative bonds.
  • Number of dative bonds in Y: 0

Final Answer

The number of dative bonds in X and Y are respectively 1 and 0.

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