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Q.

C6H5CH2OHHBrXKCNYH3O+ΔZ .What are X, Y and Z ?

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a

X:C6H5CH2CH2BrY:C6H5CH2CH2CNZ:C6H5CH2CO2H

b

X:C6H5CHO,Y:C6H5CH=CHCH,Z:C6H5CH2CO2H

c

X:C6H5CH2Br,Y:C6H5CH2CNZ:C6H5CH2CO2H

d

X:C6H5CH2Br,Y:C6H5CH2NCZ:C6H5CO2H

answer is C.

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Detailed Solution

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Chemical Reaction Sequence Explanation

Starting compound: C6H5CH2OH

Sequence of reactions:

C6H5CH2OH → HBrXKCNYH3O+, ΔZ

Identification of X, Y and Z

CompoundChemical FormulaName
XC6H5CH2BrBenzyl bromide
YC6H5CH2CNBenzyl cyanide
ZC6H5CH2COOHPhenylacetic acid

Explanation

1. Benzyl alcohol reacts with hydrogen bromide (HBr) to form benzyl bromide (X).
2. Benzyl bromide undergoes nucleophilic substitution with potassium cyanide (KCN) to give benzyl cyanide (Y).
3. Benzyl cyanide on acidic hydrolysis in the presence of heat (H3O+, Δ) gives phenylacetic acid (Z).

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