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$C_{6} H_{6} \overset{C l_{2} / A l C l_{3}}{\to} A \to_{H^{+}}^{N a O H, 623 K, 300 a t m} B \overset{C H C l_{3} / N a O H}{\to} C$ ,identify product C

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a

Chlorobenzene

b

Salicylaldehyde

c

Phenol

d

Benzene

answer is D.

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Detailed Solution

A is chlorobenzene,B is phenol, C is orthohydroxybenzaldehyde which is obtained from phenol by reimer tiemann reaction

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C6H6 →Cl2/AlCl3 A →H+NaOH,623K,300atm B →CHCl3/NaOH C ,identify product C