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Q.

Ca2B6O11+Na2CO3Δ[X]+CaCO3+NaBO2

(unbalanced equation) The incorrect choice for [X] is:

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a

The structure of anion of crystalline [X] has one boron atom  sp3 hybridized and the other three boron atoms sp2 hybridized.

b

X on heating gives a compound that in reaction with hydrogen peroxide in an alkaline medium yields a compound used as a brightener in soaps.

c

Its aqueous solution is basic.

d

[X]+ conc. H2SO4H3BO3+Na2SO4.

answer is A.

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Detailed Solution

Two boron atoms in the anion's crystalline [X] structure are sp3 hybridized, whereas the other two are sp2 hybridized.

Ca2B6O11+Na2CO3Δ[X]+CaCO3+NaBO2

Hence, the correct option is A.

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