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Q.

CaCO3(s)ΔA(s)+B(g)

A(s)cokeD(s)H2OE(g)

E(g)Cu-Tube,highTempF

F2-equivalents ofCH3Cl+AlCl3G

Incorrect statement about above series of reactions is

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a

The sum of σ and π  bonds in ‘D is 3

b

‘E’ on Bayer’s reagent gives oxalic acid

c

F to G is Electrophilic substitution of the reaction

d

The G (major) is o-xylene

answer is B.

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Detailed Solution

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This is because m− xylene is thermodynamically more stable. As expected first a mixture of o− and p− xylenes is obtained which subsequently undergo rearrangement to give the thermodynamically more stable m− xylene

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CaCO3(s)⟶ΔA(s)+B(g)A(s)⟶cokeD(s)⟶H2OE(g)E(g)→Cu-Tube,highTempFF→2-equivalents ofCH3Cl+AlCl3GIncorrect statement about above series of reactions is