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Q.

Calculate EAN of central atom/ion in K4[Fe(CN)6]

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answer is 36.

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Detailed Solution

EAN = Atomic number - Oxidation state + 2 * number of ligands 

Atomic number of Iron = 26

Oxidation number = +2

no. of ligands = 6

EAN of Fe2+= 26 -2 + (2 x 6) = 36

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