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Q.

Calculate enthalpy of combustion of  1 mole of octane C8H18(l)  using the following data:

 Given Hf0  for CO2(g), H2O(g) and C8H18(l) respectively are -390, -240 and +160 KJ/mol

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a

-67.4 MJ

b

-20.0 MJ

c

-35.5 MJ

d

–5.44 MJ

answer is A.

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Detailed Solution

C8H18(l)252O2(g)8CO2(g) + 9 H2O(l)

Hc = [8f(CO2) + 9Hf (H2O)] - [Hf(c8H18) + 252O2(g)]

= - 3120 - 2160 - 160 = - 5440kJ/mole

when 1 mole is burnt energy released = 5440KJ=5.44Mj

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