Q.

Calculate equilibrium constant (in natural number multiple of 1080 ) when sodium reduces Aluminium oxide to aluminium at 298K. ΔGf0  of Na2O(s) at 298K=377  KJ  mole1 and ΔGf0ofAl2O3  at   298K=1582KJ  mole1

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answer is 9.

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Detailed Solution

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The given reaction is 
6Na+Al2O33Na2O+2Al
So ΔG of this reaction 
3(377)(1582)=451kJ
We know that  ΔG=2.303 RT log k
logk=79.04k=9×1080

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