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Q.

Calculate normality of a salt solution [of a metal sulphatel having concentration 21.6% w/v if its superoxide has 16% by mass of oxygen.

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Detailed Solution

Equivalent weight of superoxide ion, O2=321=32
In superoxide of metal : Equivalent  of  metal = Equivalent  of superoxide ion
84E=1632 [E : Equivalent weight of metal]
E=168
Equivalent weight of metal sulphate= Equivalent weight of metal+ Equivalent weight of SO42
Equivalent weight=168+962=168+48=216
21.6%w/v means 100 ml of solution contains 21.6 g of metal sulphate:

Normality=equivalent of metal sulphateVolume of solution (in L)=21.6/2160.1=1 N

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