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Q.

Calculate solubility (mol/m3) of saturated solution of Ag3PO4, if its dilute aqueous solution at ? K has a vapour pressure of 730 mm Hg and vapour pressure of pure H2O is 740 mm Hg at TK.

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a

149.7

b

250.1

c

190.2

d

355.2

answer is B.

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Detailed Solution

P∘−PP=i×m×181000 (m≈M) 740−730730=4×M×181000 M =0.1902 mol/L or 190.2 mol/m3

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