Q.

Calculate standard molar entropy of O2(g) from the following thermodynamic data at 300 K

4Cr(s)+3O2(g)2Cr2O3(s)ΔG=2093.4kJ/molΔHfCr2O3(s)=1129.05kJ/moleSmCr(s)=24J/KmoleSmCr2O3(s)=81J/Kmol

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a

100 J/K mole

b

410 J/K mole

c

0

d

205 J/K mole

answer is B.

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Detailed Solution

The standard molar entropy is found as

ΔS=1129.05×2+2093.4300×103=549J/KmoleΔSRxn=2×814×243×x=549 x=205J/Kmole

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