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Q.

Calculate standard molar entropy O2(g) from the following thermodynamic data at 300 K :

4Cr(s)+3O2(g)2Cr2O3(s),ΔG=2093.4 kJ/mo1ΔHfCr2O3(s)=1129.05 kJ/moleSmCr(s)=24 J/K moleSmCr2O3(s)=81 J/K mole

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a

 100 J/K mole

b

0

c

 205 J/K mole

d

410 J/K mole

answer is B.

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Detailed Solution

4Cr(s)+3O22Cr2O3(s) ΔG=2093.4 kJ/moleΔG=ΔHTΔSΔH=2ΔHfCr2O3=2×(1129.05) kJΔS=2SmCr2O3(s)4SmCr(s)3SmO2 =2×814×243SmO2 J/K
Substituting the values
2093.4=(2×1129.05) 30081×24×243SmO2103SmO2=205 J/K mole 

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