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Q.

Calculate the CFSE for K4Fe(CN)6

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a

1.2Δ0

b

2.4Δ0

c

2.0Δ0

d

1.6Δ0

answer is A.

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Detailed Solution

In FeCN64-, Fe has +2 oxidation state and its outer electronic configuration becomes 3d5. As CN- is a strong ligand, so all electrons of 3d gets paired in t2g orbitals and eg orbitals remains empty, t2g6eg0.

CFSE=-0.4(number of electrons in t2g)+0.6(number of electrons in eg)            =-0.4(6)+0.6(0)            =2.4Δ0

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