Q.

Calculate the change in pH when a 0.1 M solution of CH3COOH in water at 25° C is diluted to a final concentration of 0.01MKa=1.85×105

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a

+ 0.6 

b

+ 0.5 

c

+ 0.4 

d

+ 0.47 

answer is A.

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Detailed Solution

CH3COOH Weak acid. 

ph=12(pkalog z)

 pH initial =12 Lpka- logcinitial

pH final=12pxalogCfinal 

ΔpH=pH final PHinitial

=12logCinitial logCfinal 

ΔpH=12[log(0.1)log(0.01)]

=12[(1)(2)].

Δph=12[1+2]=12

=0.5

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Calculate the change in pH when a 0.1 M solution of CH3COOH in water at 25° C is diluted to a final concentration of 0.01M⋅Ka=1.85×10−5