Q.

Calculate the equilibrium constant for the reaction, 
   Zn(s)+Cu2+(aq)Zn2+(aq)+Cu(s) 
                                                          Given, Ecell =1.1V

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a

2×1034

b

2×1032

c

2×1037

d

2×1039

answer is C.

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Detailed Solution

Zn(s)+Cu2+(aq)Zn2+(aq)+Cu(s)
0=Ecell=Ecell2.303RT2FlogZn2+Cu2+
or     Ecell=2.303RT2FlogZn2+Cu2+
But at equilibrium Zn2+Cu2+=KC
               Ecell =0.059V2logKC=1.1VlogKC=1.1V×20.059V=37.288        KC=2×1037 at 298K

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