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Q.

Calculate the equilibrium pressure (in Pascal) for the conversion of graphite to diamond at 25C. The densities of graphite and diamond may be taken to be 2.20 and 3.40g/cc respectively independent of pressure. (Express your answer in scientific notation x×10y and write the value of y.)

 [ Given : ΔG298C(graphite) C(diamond) =2900J/mol]

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answer is 9.

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Detailed Solution

Conversion of graphite to diamond,

C (graphite) 12 gC (diamond) 12 g

Graphite, Vm=122.2=5.45cc

Diamond, Vm=123.4=3.53cc

dG=VdPΔGΔGdΔG=ΔVPPdPΔG=(3.535.45)×103×(P1)×100

 P=1.5×109N/m2

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