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Q.

Calculate the heat produced (in kJ) when 224 gm of CaO is completely converted to CaCO3 by

reaction with CO2 at 27°C in a container of fixed volume.  

Given : ΔHf°(CaCO3,s) =  1207kJ/mol

ΔHf°(CaO,s) =  635kJ/mol

ΔHf°(CO2,g) =  394kJ/mol [Use R = 8.3 K-1mol-1]                                           

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a

 702.04 kJ

b

721 kJ  

c

167.94 k Cal

d

167.94 Cal 

answer is A, C.

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Detailed Solution

CaO + CO2 CaCO3 ΔrH = [ΔHCaCO3(ΔHCaO + ΔHCaO)]

56gr                                 ΔfH

224gr

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