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Q.

Calculate the mass of a non-volatile solute (molecular mass 40), which should be dissolved in 114 g of octane to reduce its vapour pressure to 80 %. 

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answer is 8.

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Detailed Solution

Ps=80100P

WB is the weight of the solute and molecular weight of solute, MB=40 g mol 

Weight (WA) of solvent;  WA=114 g

Molecular weight (MA) of octane  C8H18=(8×12)+(18×1)=114 g mol 

We know, that 

             PPSP=WBMB×MAWAP80100PP=WB×11440×114WB=8 g

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