Q.

Calculate the mole fraction of H2SO4 in a solution containing 98% H2SO4 by mass.

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answer is 1.

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Detailed Solution

98%H2SO4 means 98 parts of H2SO4 is present in 100 parts of solution.
wt of H2SO4 = 98; molar mass of H2SO4 = 98
no.of moles of H2SO4=9898=1
wt of H2O = 100 – 98 = 2gm
m.w of H2O =18
no.of moles of H2O = 218=0.1
Total moles in solution = 1 + 0.1 = 1.1
mole fraction of
H2SO4= No.of moles of H2SO4 Total moles of solution =11.1=0.9

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