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Q.

Calculate the moles of BaSO4 obtained in each case if excess of BaCl2 is reacted with :

(a) H2SO4 solution produced from collecting only SO3 present in 100 gm of 104.5 % oleum and reacted with excess of water.

(b) Only H2SO4 taken from 100 ~ 104.5 % oleum 

(c) H2SO4 solution obtained when 4.5 g water is added to 100 gm oleum labelled as 104.5%.
Write the nearest integral value of (a) + (b) + (c) .

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answer is 2.

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Detailed Solution

(a) 2080=14=0.25 mole  (b) 8098=0.816 mole

(c) 104.598=1.066 mole

(a) + (b) + (c) =2.082  mole ~2

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